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131.
The Powder River Basin (PRB) of Wyoming and Montana contains significant coal and coal bed natural gas (CBNG) resources. CBNG extraction requires the production of large volumes of water, much of which is discharged into existing drainages. Compared to surface waters, the CBNG produced water is high in sodium relative to calcium and magnesium, elevating the sodium adsorption ratio (SAR). To mitigate the possible impact this produced water may have on the quality of surface water used for irrigation, the State of Montana passed water anti‐degradation legislation, which could affect CBNG production in Wyoming. In this study, we sought to determine the proportion of CBNG produced water discharged to tributaries that reaches the Powder River by implementing a four end‐member mixing model within a Bayesian statistical framework. The model accounts for the 87Sr/86Sr, δ13CDIC, [Sr] and [DIC] of CBNG produced water and surface water interacting with the three primary lithologies exposed in the PRB. The model estimates the relative contribution of the end members to the river water, while incorporating uncertainty associated with measurement and process error. Model results confirm that both of the tributaries associated with high CBNG activity are mostly composed of CBNG produced water (70–100%). The model indicates that up to 50% of the Powder River is composed of CBNG produced water downstream from the CBNG tributaries, decreasing with distance by dilution from non‐CBNG impacted tributaries from the point sources to ~10–20% at the Montana border. This amount of CBNG produced water does not significantly affect the SAR or electrical conductivity of the Powder River in Montana. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
132.
Abstract

Knowledge of the hydrochemical dynamics of the trace metal manganese (Mn) in upland catchments is required for water quality management. Stream water Mn and other solutes and flow were monitored in two upland catchments in northern England with different soils: one dominated by peat (HS7), the other by mineral soils (HS4). Maximum Mn concentrations occurred at different times in the two catchments: in summer baseflow at HS4 and during late summer storm events at HS7. A two-component chemical mixing model was used to identify the hydrological processes controlling Mn concentrations in stream water. This approach was more successful for HS4 than HS7, probably because of different processes of Mn release in the two catchments and also difficulties in selecting conservative solutes. Factor analysis of the stream water chemistry data set for each catchment was more useful in identifying the controls on Mn release into runoff. The factors indicate that the main source of Mn at HS4 is the hydrological pathway supplying summer baseflow, whereas at HS7 Mn is released during the rewetting of dried peat soils. Manganese concentrations in stream water in upland catchments appear to depend on soil type and antecedent moisture conditions. This has implications for the design of sampling strategies in upland catchments and also for managing the quality of water supplies from such areas.  相似文献   
133.
The lower coastal plain of the Southeast USA is undergoing rapid urbanisation as a result of population growth. Land use change has been shown to affect watershed hydrology by altering stream flow and, ultimately, impairing water quality and ecologic health. However, because few long‐term studies have focused on groundwater–surface water interactions in lowland watersheds, it is difficult to establish what the effect of development might be in the coastal plain region. The objective of this study was to use an innovative improvement to end‐member mixing analysis (EMMA) to identify time sequences of hydrologic processes affecting storm flow. Hydrologic and major ion chemical data from groundwater, soil water, precipitation and stream sites were collected over a 2‐year period at a watershed located in USDA Forest Service's Santee Experimental Forest near Charleston, South Carolina, USA. Stream flow was ephemeral and highly dependent on evapotranspiration rates and rainfall amount and intensity. Hydrograph separation for a series of storm events using EMMA allowed us to identify precipitation, riparian groundwater and streambed groundwater as main sources to stream flow, although source contribution varied as a function of antecedent soil moisture condition. Precipitation, as runoff, dominated stream flow during all storm events while riparian and streambed groundwater contributions varied and were mainly dependent on antecedent soil moisture condition. Sensitivity analyses examined the influence of 10% and 50% increases in analyte concentration on EMMA calculations and found that contribution estimates were very sensitive to changes in chemistry. This study has implications on the type of methodology used in traditional forms of EMMA research, particularly in the recognition and use of median end‐member water chemistry in hydrograph separation techniques. Potential effects of urban development on important hydrologic processes (groundwater recharge, interflow, runoff, etc.) that influence stream flow in these lowland watersheds were qualitatively examined. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
134.
潮沟成因类型及其影响因素的探讨   总被引:14,自引:0,他引:14  
潮沟是潮坪上最活跃的微地貌单元。从成因角度分出了滩面水流冲剧型、潮流辐聚侵蚀型、陆源水流侵蚀继承型和泻湖广海间潮流侵蚀型等四种潮沟类型。根据各地潮沟发育程度的明显差异,提出了影响潮沟发育的七个重要因素。  相似文献   
135.
Comparisons of maps and aerial photographs dating from the late 1700s to the present document the recent development of an 8 km2 saltmarsh that is situated behind a barrier spit in southern Maine. Tidal channels that were relatively narrow in 1794 became wider by 1872. The reduction of marsh bordering tidal channels is interpreted as evidence that marsh accretion could not keep pace with rising sea-level. This suggests that the rate of sea-level rise had increased, although a change in discharge or sediment load caused by extensive settlement and land clearance may also have been involved. Meander patterns of the tidal streams changed considerably throughout the time period covered by the maps, demonstrating that the streams of this marsh are more dynamic than some others that have been widely reported in the literature. These differences in stream dynamics are probably related to the differences in sedimentological structure of the marshes. Between 1872 and 1956 the barrier spit eroded on its inside (shoreward) edge, probably in response to the construction of riprapping and houses along the spit, and the subsequent reduction of overwash and aeolian transport of sediment. Modification of the tidal inlet and adjacent marsh during the 1960s, including jetty construction, dredging, and filling of portions of the marsh surface, affected the marsh only locally. One tidal stream has been migrating rapidly apparently in response to compaction of peat by dredge spoils and consequent local disruption of the marsh hydrology. Except for this migration, erosion of the marsh edge occurred immediately after the inlet modifications; planimetric changes in the marsh and its streams have been minor since then.  相似文献   
136.
根据微量元素e1、e2、e3总分配系数的相对大小,源区混合-结晶分异复合过程在它们的比值-比值相关图上造成三种综合效应。新疆阿尔泰花岗岩微量元素的比值-比值相关图清晰地反映了三种效应,暗示着源区混合-结晶分异复合过程。源区混合机制可能为沉积物质在沉积盆地里的掺合。混合端员可能为:1)成熟度差异悬殊的陆源碎屑物质;2)陆源碎屑与基性火山物质。  相似文献   
137.
This paper reports results and analysis of210Pb-activity measurements in 51 lake-sediment cores from 32 lakes in the four PIRLA (Paleoecological Investigations of Recent Lake Acidification) project regions (Adirondack Mountains [New York], Northern New England, Northern Florida, and the Northern Great Lakes States). General application of the Constant Rate of Supply (Constant Flux) model for210Pb dating is valid for lakes in the PIRLA study, although application of the model is equivocal in a few lakes.210Pb inventories and profiles are replicable among closely spaced cores within a lake. Specific210Pb activity in surface sediments is negatively correlated with bulk sediment accumulation rate in seepage lakes, but not in drainage lakes. Drainage lakes with lower pH have lower unsupported210Pb inventories in sediments, but the relationship does not occur in seepage lakes.210Pb profiles in only seven of the cores, all from either the Adirondacks or the northern Great Lakes states, exhibit exponential decay curves. Deviations from an exponential profile include a flattening of the profile in the top few cm or excursions of one or a few measurements away from an exponential curve.210Pb dates typically agree with other chronostratigraphic markers, most of which are subject to greater uncertainty. Several hypotheses, including sediment mixing, hydrologic regime, sediment focusing, and acidification, are proposed to explain variation of210Pb distribution among lakes and regions. Hydrologic factors exert control on unsupported210Pb inventories in PIRLA lakes, and there is a strong focusing effect in drainage lakes but a weak focusing effect in seepage lakes.This is the third of a series of papers to be published by this journal following the 20th anniversary of the first application of210Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.  相似文献   
138.
华南花岗岩物源成因特征与陆壳演化   总被引:15,自引:1,他引:15  
华南不同时代的花岗岩按物质来源及成因可划分为:幔源(分异)系列:幔-壳混源(同熔)系列;壳源改造(重熔)系列和幔-壳混源碱性系列等四个不同的系列,简要阐述了划分四类系列的岩石学、地球化学的依据。侧重根据Sm-Nd、Rb-Sr同位素成分,以二元混合模型计算了花岗岩源区物质组成中,上壳和亏损地幔组份各占的比例。在此基础上探讨了不同物源成因系列花岗岩形成与华南陆壳演化的内在联系:东安、雪峰旋回褶皱系阶段花岗岩物源成因类型比较多样,有幔源(分异)系列、不成熟壳源、成熟壳源改造(重熔)系列等;加里东,海西期以陆壳改造(重熔)系列为主;印支、燕山期活化区(地洼)阶段,在地幔活化激发下,中国东部陆缘形成幔—壳混源(同熔)系列花岗岩和相应的火山岩;但沿内部断裂带,在壳下地幔热传输及构造作用下引起陆壳重熔,形成属于壳源改造(重熔)系列花岗岩。同位素的研究证明了:地洼阶段的构造-岩浆活动主要动力是来自壳下地幔的活化。  相似文献   
139.
吉林省南部下元古界集安群地质特征与沉积期古环境分析   总被引:5,自引:0,他引:5  
王福润 《吉林地质》1991,10(2):31-41
根据集安群地质特征,岩石化学,稳定同位素特征分析认为:蚂蚁河组沉积期古环境为强氧化泻湖相;荒岔沟组沉积期为强还原的泻湖相、大东岔组沉积期为开阔正常浅海潮坪相。集安群从发生发展到结束古环境演化规律是:构造上,由优地槽向冒地槽演化,气候上由炎热向温湿演化;古地理环境从有障壁的局限海变为无障壁的开阔海;从咸化海向正常海,从泻湖相向潮坪相转化。  相似文献   
140.
斜方顽火辉石-正铁辉石(MgSiO_3-FeSiO_3)中Fe~(2+)及Mg~(2+)在M_1和M_2两种非等效位置上进行非理想混合。研究表明,辉石的等压热容(C_p)强烈依赖于组成,呈非线性关系,可表示为: 低温时热容的非理想混合效应显著,随着温度的升高,等温热容曲线(空间热容曲面)从一个极大值点(峰脊)分解为两个极大值点(峰脊),且逐渐趋向于理想混合热容直线(或平面)。  相似文献   
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